This is how to move the Exchange Catalog files to a different drive :
Open the exchange management shell and execute the following command
Set-MailboxDatabase -Identity databasename -IndexEnabled $false
Stop the Microsoft Exchange Search Indexer service
You can move your old files to the new directory, in my case the files were in the following dir :
The files will be in the parent directory were the Exchange Mailbox database are also located.
Now start the Microsoft Exchange Search Indexer service and execute the following command :
Set-MailboxDatabase -Identity databasename -IndexEnabled $false